I got a similar error. According to the man page there are some debug options --debug and -no-daemon
I tried
gnome-settings-daemon --debug --no-daemon
from a console
and I got an error message about segfaults with ffmpeg.
ERROR: Caught a segmentation fault while loading plugin file:
/usr/lib/gstreamer-0.10/libgstffmpeg.so
Please either:
- remove it and restart.
- run with --gst-disable-segtrap and debug.
source: http://www.debianhelp.org/node/6711